Push the Color Contrast

Well I had to change my schedule around so I am working on my Matte Paintings and Skys. Here are ideas for really pushing the color to opposit ends on the spectrum:

Talk about nice shot!!!

The only challenge with this is what it looks like from the front view. It's all Overcast lighting so I will have to really fake create a new look. Perhaps I'll add blue to the top of the sky, then continue the blue going back into the front view??? I need more sky references from different angles.

Storywise, it would make sense if there still is a sense of blues behind my main character, sense that's where he's coming from. Perhaps, I'll have the cloud cover subtley change, so we see his change also.